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Organorhodium chemistry : ウィキペディア英語版
Organorhodium chemistry
Organorhodium chemistry is the chemistry of organometallic compounds containing a rhodium-carbon chemical bond, and the study of rhodium and rhodium compounds as catalysts in organic reactions.〔''Synthesis of Organometallic Compounds: A Practical Guide'' Sanshiro Komiya Ed. S. Komiya, M. Hurano 1997〕
Stable organorhodium compounds and transient organorhodium intermediates are used as catalyst such as in olefin hydroformylation, olefin hydrogenation, olefin isomerization and the Monsanto process
==Description==

Organometallic rhodium compounds share many characteristics with those of cobalt (see organocobalt compounds), which is also in group 9. Rhodium can exist in oxidation states of -III to +IV, but rhodium(I) and rhodium(III) are the most common. Rhodium(I) compounds (d8 configuration) can occur with square planar or trigonal bipyramidal geometries, while rhodium (III) compounds (d6 configuration) typically have an octahedral geometry.〔

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